Quantum tunnelling can at times be the cause of kinetic isotope effects, and in these cases conventional wisdom has been that molecules with isotopes of larger mass will react more slowly.
This formulation enables the calculation of rate constants and kinetic isotope effects for comparison to experiment. Applications to PCET reactions in solution, enzymes, and electrochemical systems ...
A study published in National Science Review reveals that carbon-14 (C-14) from algae can integrate into zebrafish ...
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