Paint can peel for a variety of reasons, including too much moisture, using the wrong product, and poor wall preparation.
Oil-based paint has a high concentration of pigment and will typically take longer to dry than either acrylic or latex paint.
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And why is it so expensive? Oil paint has been used for hundreds of years. It's made from a drying oil, like flaxseed, and pigment sometimes with fillers and thickeners added to the mix.